منابع مشابه
N,O-Type Carborane-Based Materials
This review summarizes the synthesis and coordination chemistry of a series of carboranyl ligands containing N,O donors. Such carborane-based ligands are scarcely reported in the literature when compared to other heteroatom-containing donors. The synthetic routes for metal complexes of these N,O-type carborane ligands are summarized and the properties of such complexes are described in detail. ...
متن کاملSynthesis and hydrogen sorption properties of carborane based metal-organic framework materials.
Metal-Organic Framework Materials Omar K. Farha,† Alexander M. Spokoyny,† Karen L. Mulfort,†,‡ M. Frederick Hawthorne,§ Chad A. Mirkin,*,† and Joseph T. Hupp*,† Department of Chemistry and International Institute for Nanotechnology, Northwestern UniVersity, 2145 Sheridan Road, EVanston, Illinois 60208, Chemistry DiVision, Argonne National Laboratory, Argonne, Illinois 60439, and International I...
متن کاملIcosahedral metallacarborane/carborane species derived from 1,1'-bis(o-carborane).
Examples of singly-metallated derivatives of 1,1'-bis(o-carborane) have been prepared and spectroscopically and structurally characterised. Metallation of [7-(1'-1',2'-closo-C2B10H11)-7,8-nido-C2B9H10](2-) with a {Ru(p-cymene)}(2+) fragment affords both the unisomerised species [1-(1'-1',2'-closo-C2B10H11)-3-(p-cymene)-3,1,2-closo-RuC2B9H10] (2) and the isomerised [8-(1'-1',2'-closo-C2B10H11)-2...
متن کاملExtremely Electron-Rich, Boron-Functionalized, Icosahedral Carborane-Based Phosphinoboranes.
We have prepared the first examples of B9-connected trivalent aryl and alkyl phosphinoborane species via Pd-catalyzed phosphination of 9-iodo-meta-carborane. Our studies highlight the unique electronic features of the B9-connected meta-carboranyl moiety as compared to its C1-based analogue. This work suggests that the B9-functionalized meta-carboranyl substituent in these ligands exhibits more ...
متن کاملIntramolecular hydrogen bonding stabilizes the nuclearity of complexes. A comparative study based on the H-carborane and Me-carborane framework.
New dinuclear carboranylcarboxylate-bridged and mononuclear copper(ii) compounds containing the 1-CO2H-2-H-1,2-closo-C2B10H10 carborane ligand () have been synthesized from the previously synthesized dinuclear compound [Cu2(μ-L)4(THF)2], . Reaction of with CuSO4 in THF leads to the dinuclear compound [Cu2(μ-L)4(THF)2], . The reaction of with different terminal pyridyl ligands leads to the forma...
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ژورنال
عنوان ژورنال: Crystals
سال: 2016
ISSN: 2073-4352
DOI: 10.3390/cryst6050050